Preformed Thermoplastic Safety Data
Provided below is all the current safety data we have on our preformed thermoplastic product. Scroll down to the bottom of the page to download the pdf for reference!
Identification
Product identifier - Preformed Thermoplastic
Synonyms - Thermoplastic Road Marking/Traffic Marking- Torch-Applied
Recommended use - Traffic Marking
Recommended restrictions - None known
Manufacturer - Ozark Materials, LLC, 591 Glendale Ave. Greenville, AL 36037
General Assistance - 334-213-2995
E-Mail - [email protected]
Contact Person - Derron Henderson
Emergency Telephone - 770-355-4477
Hazard(s) Identification
Physical hazards
- None known
- Acute toxicity, inhalation - Category 4
- Serious eye damage/eye irritation - Category 2A
- Germ cell mutagenicity - Category 2
- Carcinogenicity - Category 1A
- Specific target organ toxicity, single exposure; Respiratory tract irritation - Category 3
- Specific target organ toxicity, repeated exposure - Category 1
Elements
Signal word - Danger
Hazard statement - Harmful if inhaled. Causes serious eye irritation. Suspected of causing genetic defects.
May cause cancer. May cause respiratory irritation. Causes damage to lungs through
prolonged or repeated exposure.
Precautionary statement Prevention - Wear protective gloves/protective clothing/eye protection/face protection. Wash skin
thoroughly after handling. Obtain special instructions before use. Do not handle until
all safety precautions have been read and understood. Use only outdoors or in a well-ventilated
area. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or
smoke when using this product.
Response IF INHALED: Remove person to fresh air and Keep at rest in a position comfortable for
breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. IF eye irritation persists: Get medical
advice/attention. IF exposed or concerned: Get medical advice/attention. Get medical
advice/attention if you feel unwell.
Storage Disposal - Store locked up. Store in a well-ventilated place. Keep container tightly closed.
Disposal Dispose of contents/container in accordance with local/regional/national/international
regulations.
Hazard(s) not otherwise None known.
Composition/information on ingredients
Mixtures
| Chemical name | CAS number | % |
| Calcium carbonate | 1317-65-3 | 30-45 |
| Titanium dioxide | 13463-67-7 | 0-15 |
| Carbon black | 1333-86-4 | <3 |
| Barium sulfate | 7727-43-7 | 0-2 |
| Quartz | 14808-60-7 | 0-2 |
The criteria for listing components in the composition are as follows: Carcinogens are listed when present at 0.1% or greater; components which are otherwise hazardous according to OSHA are listed when present at 1.0% or greater. Non-hazardous components may be listed at 3.0% or greater if not proprietary in nature. This is not intended to be complete compositional disclosure. Refer to section 15 for applicable states right-to-know and other regulatory information.
First-aid measures
Inhalation - Consult a physician if respiratory tract irritation occurs.
Skin contact - Cool affected area as soon as possible in cold water; be sure to leave plastic in place.
Place furacin soluble dressing on plastic & surrounding area. Cover affected area with
protective bandage. Consult a physician in case of a severe burn.
Eye contact - Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Get medical attention.
Ingestion - Rinse mouth thoroughly. Never give anything by mouth to a victim who is
unconscious or is having convulsions. Get medical attention immediately.
Most important symptoms/effects, acute & delayed - Respiratory tract irritation, thermal burns from molten material, chronic exposure may pose a silicosis risk.
Indication of immediate medical attention & special treatment needed - In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
General information - If exposed or concerned: get medical attention/advice. Ensure that medical personnel
are aware of the material(s) involved, and take precautions to protect themselves.
Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before re-use.
Fire-fighting measures
Suitable extinguishing media - Water spray, dry chemical, CO2, Foam
Unsuitable extinguishing media - Strong oxidizing agents.
Specific hazards arising from the chemical - Carbon Monoxide.
Special protective equipment and precautions for firefighters - Wear self contained breathing apparatus in the positive mode to
avoid smoke and fumes. Avoid direct contact with water to
avoid splattering of molten plastic.
Accidental release measures
Personal precautions, protective equipment
and emergency procedures - Keep unnecessary personnel away. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing. See
Section 8 of the SDS for Personal Protective Equipment.
Methods and materials for containment
and cleaning up - Granular material may be scooped up or swept. Allow molten material
to cool and then dispose of in accordance with Federal, State and Local
Regulations.
Handling and storage
Precautions for safe handling - Avoid inhaling dust particles. Wash hands after use. Do NOT eat, drink, or
smoke in work areas.
Conditions for safe storage, including
any incompatibilities - Keep in a ventilated area when possible. Store in a cool, dry area and away from acids or oxidizers.
Exposure controls/personal protection
Occupational exposure limits
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
| Components | Type | Value |
| Calcium carbonate (CAS#1317-65-3) | PEL (TWA) | (total dust), 5 mg/m3 (respirable) |
| Titanium dioxide (CAS#13463-67-7) | PEL (TWA) | 15 mg/m3 |
| Carbon black (CAS#1333-86-4) | PEL (TWA) | 3.5 mg/m3 |
| Barium sulfate (CAS#7727-43-7) | PEL (TWA) | (total dust), 5 mg/m3 (respirable) |
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
| Components | Type | Value |
| Calcium carbonate (CAS#1317-65-3) | 8-hour TWA | (total dust), 5 mg/m3 (respirable) |
| Titanium dioxide (CAS#13463-67-7) | 8-hour TWA | 15 mg/m3 |
| Carbon black (CAS#1333-86-4) | 8-hour TWA | 3.5 mg/m3 |
| Barium sulfate (CAS#7727-43-7) | 8-hour TWA | (total dust), 5 mg/m3 (respirable) |
US. OSHA Table Z-2 (29 CFR 1910.1000)
None of the components in this product is listed.
US. OSHA Table Z-3 Mineral dusts (29 CFR 1910.1000)
| Components | Type | Value |
| Quartz (CAS#14808-60-7) | TWA | TWA 10 mg/m3 (respirable) %SiO2+2 30 mg/m3 (Total dust) %SiO2+2 |
US. ACGIH Threshold Limit Values
| Components | Type | Value |
| Titanium dioxide (CAS#13463-67-7) | TLV | 10 mg/m3 (total dust) |
| Carbon black (CAS#1333-86-4) | TLV | 3 mg/m3 (Inhalable) |
| Barium sulfate (CAS#7727-43-7) | TLV | 5 mg/m3 |
US. NIOSH: Pocket Guide to Chemical Hazards
| Components | Type | Value |
| Calcium carbonate (CAS#1317-65-3) | REL (TWA) | 10 mg/m3 (total dust), 5 mg/m3 (respirable) |
| Carbon black (CAS#1333-86-4) | REL (TWA) | 3.5 mg/m3 |
| Barium sulfate (CAS#7727-43-7) | REL (TWA) |
0 mg/m3 |
| Quartz (CAS#14808-60-7) | REL (TWA) | Ca 0.05 mg/m3 |
Appropriate engineering controls - Local exhaust recommended when generating excessive levels of airborne
dust/vapors when heating plastic.
Individual protection measures, such as personal protective equipment
Eye/face protection - Safety glasses; Eye goggles covered with face shield when handling molten plastic.
Skin protection
Hand protection - Avoid exposures – obtain special instructions before use. Wear protective gloves.
Other - Wear heat-resistant protective clothing & gloves when handling molten plastic. Always carry first aid kit, water & ice during application.
Respiratory protection Use an approved/certified respirator or equivalent.
Thermal hazards - Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations - Always wash hands after use & before eating, drinking or any other personal activity.
Physical and chemical properties
Appearance
Physical state - Solid
Form - Granular
Color - White, Yellow, Black, Blue, Red, Green
Odor - Alkyd oil
Odor threshold - Not Available
pH - Not Available
Melting point/freezing point - 100-135°C (212-275°F) (Softening Point, R&B Method)
Initial boiling point and boiling range - Not Available
Flashpoint - >246.11 °C (>475 °F)(Closed Cup)
Evaporation rate - Not Available
Flammability (solid, gas) - Not Available
Upper/lower flammability or explosive limits
Flammability limit – lower (%) Not Available
Flammability limit – upper (%) Not Available
Explosive limit - lower (%) Not Available
Explosive limit - upper (%) Not Available
Vapor pressure - Not Available
Vapor density - Not Available
Relative density (specific gravity) - 1.75-2.25
Solubility (water) - Negligible
Partition coefficient (n-octanol/water) - Not Available
Auto-ignition temperature - Not Available
Decomposition temperature - Not Available
Viscosity - Not Available
Stability and reactivity
Reactivity - Not generally reactive under normal conditions
Chemical stability - Stable at <246.11 °C (<475 °F)
Possibility of hazardous reactions - Polymerization will not occur
Conditions to avoid - Temperatures above 260 °C (500 °F), incompatible materials
Incompatible materials - Acids, alum, ammonium salts, mercury & hydrogen, fluorine, magnesium
Hazardous Decomposition Products - Carbon Monoxide, Carbon Dioxide
Toxicological information
Information on likely routes of exposure
Ingestion - Do not ingest.
Inhalation - Harmful if inhaled. Overexposure may cause temporary respiratory
irritation.
Skin contact - Moderate irritation, thermal burns may occur from molten material.
Eye contact - Particulates may cause irritation to the eyes.
Symptoms related to the physical,
chemical & toxicological characteristics - Respiratory tract irritation, thermal burns from molten material, chronic exposure may pose a silicosis risk.
Delayed & immediate effects & chronic effects from short-& long-term exposure - Redness, pain, and inflammation of the eyelids, coughing, sneezing, dyspnea, respiratory tract irritation, chronic rhinitis.
Numerical measures of toxicity
| Components | Test | Species | Test Results |
| Titanium dioxide (CAS# 13463-67-7) | Oral LD50 | Rat | > 5000 mg/kg |
| Inhalation LC50 | Rat | >3.43 mg/l |
Skin corrosion/irritation - Based on available data, the classification criteria are not met.
Serious eye damage/eye irritation - Causes serious eye irritation.
Respiratory or skin sensitization
Respiratory sensitization - No data available.
Skin sensitization - No data available.
Germ cell mutagenicity - Suspected of causing genetic defects.
Carcinogenicity - May cause cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Titanium dioxide (CAS#13463-67-7) - Group 2B “Possibly Carcinogenic to Humans”.
Carbon Black (CAS#1333-86-4) - Group 2B “Possibly Carcinogenic to Humans”.
Quartz (CAS# 14808-60-7) - Group 1 " Carcinogenic to Humans".
NTP Report on Carcinogens
Quartz (CAS# 14808-60-7) - Group Known “Known to be a Human Carcinogen”.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) - None of the components in this product is listed.
Reproductive toxicity - No data available.
Specific target organ toxicity – single exposure - May cause respiratory irritation.
Specific target organ toxicity – repeated exposure - Causes damage to lungs through prolonged or repeated exposure.
Aspiration hazard - No data available.
Ecological information
| Numerical measures of toxicity | Test | Species | Test Results |
| Titanium dioxide (CAS# 13463-67-7) | Crustacea EC50 | Water flea (Daphnia magna ) | >100 mg/l, 48 Hours |
| Persistence and degradability | Not available | ||
| Bioaccumulative potential | Not available | ||
| Mobility in soil | Not available | ||
| Other adverse effects | Not available |
Disposal considerations
Disposal instructions - Dispose of in accordance with applicable Federal, State and Local Regulations.
Hazardous waste code
US RCRA Hazardous Waste U List: Not available.
Contaminated packaging - Offer rinsed packaging material to local recycling facilities.
Transport information
| In Accordance with DOT | Not regulated for transport. |
| In Accordance with IMDG | Not regulated for transport. |
| In Accordance with IATA | Not regulated for transport. |
Regulatory information
US federal regulations - This product is a “Hazardous Chemical” as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
None of the components in this product is regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Calcium carbonate (CAS#1317-65-3)
Titanium dioxide (CAS#13463-67-7)
Carbon black (CAS#1333-86-4)
Barium sulfate (CAS#7727-43-7)
Quartz (CAS#14808-60-7)
CERCLA Hazardous Substance List (40 CFR 302.4) - None of the components in this product are regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance - None of the components in this product are listed.
SARA 311/312 Hazardous chemical - Yes
SARA 313 (TRI reporting) - None of the components in this product are listed.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
None of the components in this product is listed.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
None of the components in this product is listed.
Safe Drinking Water Act (SDWA)
None of the components in this product is listed.
US State regulations - WARNING: This product contains chemicals known to the state of California to cause cancer.
US. Massachusetts RTK – Substance List
Calcium carbonate (CAS #1317-65-3)
Titanium dioxide (CAS #13463-67-7)
Carbon black (CAS #1333-86-4)
Barium sulfate (CAS # 7727-43-7)
Quartz (CAS #14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
Calcium carbonate (CAS #1317-65-3)
Titanium dioxide (CAS #13463-67-7)
Carbon black (CAS #1333-86-4)
Barium sulfate (CAS # 7727-43-7)
Quartz (CAS #14808-60-7)
US. Pennsylvania Worker and Community Right-to-Know Law
Calcium carbonate (CAS #1317-65-3)
Titanium dioxide (CAS #13463-67-7)
Carbon black (CAS #1333-86-4)
Barium sulfate (CAS # 7727-43-7)
Quartz (CAS #14808-60-7)
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Substance List
Carbon black (CAS #1333-86-4)
Quartz (CAS #14808-60-7)
Canada regulations
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR).
WHMIS classification D2A Materials Causing Other Toxic Effects (very toxic)
International Inventories
| Country(s) or region | Inventory name | On inventory (yes/no)* |
| Australia | Australian Inventory of Chemical Substances (AICS) | No |
| Canada | Domestic Substances List (DSL) | Yes |
| Canada | Non- Domestic Substances List (NDSL) | No |
| China | Inventory of Existing Chemical Substances in China (IECSC) | No |
| Europe | European Inventory of Existing Commercial Chemical Substances (EINECS) | No |
| Europe | European List of Notified Chemical Substances (ELINCS) | No |
| Japan | Inventory of Existing and New Chemical Substances (ENCS) | Yes |
| Korea | Existing Chemical List (ECL) | Yes |
| New Zealand | New Zealand Inventory | No |
*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the
governing country(s).
